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Family: Florals

Aldehydes: the synthetic sparkle behind Chanel No. 5

Aldehydes in perfumery are synthetic molecules with a powerful, fresh smell, often green or citrusy, that make a composition radiate. They became famous in 1921, when Ernest Beaux overdosed them in Chanel No. 5.

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What are aldehydes in perfume?

Aldehydes are organic compounds carrying a formyl group, and the volatile ones have strong odours. Traces of many aldehydes occur naturally in essential oils, among them cinnamaldehyde and vanillin. The chemistry entry on aldehydes notes that some are produced only on a small scale as ingredients for flavours and perfumes, and that fresh, green, citrusy and nutty notes in perfumes are often due to aldehydes.

What do aldehydes smell like?

Each aldehyde has its own smell. In No. 5, dodecanal brings lily and violet tones and 2-methylundecanal a vague orange note, according to French accounts of the formula. Ernest Beaux's student Constantin Weriguine said the aldehyde Beaux used had the clean note of the Arctic, "a melting winter note". What aldehydes share is their effect: they boost the materials around them.

Why did aldehydes make history in No. 5?

Chanel launched No. 5, composed by Ernest Beaux, on 5 May 1921. The history of Chanel No. 5 explains that Beaux reworked a rose and jasmine base, increased the orris, and used aldehydes as aroma boosters. Chanel picked the fifth of the vials Beaux presented, numbered 1 to 5 and 20 to 24, hence the name. According to the same account, a laboratory assistant mistook a full-strength mixture for a ten percent dilution, which loaded the formula with a quantity of aldehyde never used before.

What should you know about aldehydes?

Aldehydes belong to the florals family because their most famous use sets them on a floral heart: rose, jasmine and orris in No. 5. Most aldehydes tend to oxidise during storage. The Class on natural versus synthetic places them in the history of fragrance chemistry.

Often paired with

Rose Jasmine Orris Ylang-ylang

Further reading

Aldehydes in the feed

In the Classes

Small heap of white needle-shaped vanillin crystals on a dark surface

Class no. 4 · 6 min read

Natural vs synthetic fragrance: what chemistry gave perfume

Since the 1860s, perfumery has mixed natural materials with synthetic molecules, and neither is better or safer by default. You'll be able to date the molecules that changed perfume, from coumarin to Iso E Super, and read the word natural on a label without reading too much into it.